.png)
8-HYDROXYJULOLIDINE-9-ALDEHYDE
Basic Information
- CAS No.:63149-33-7
Physical properties
Product Description
Good factory exports good 8-HYDROXYJULOLIDINE-9-ALDEHYDE 63149-33-7
- Molecular Formula:C13H15NO2
- Molecular Weight:217.268
- Melting Point:69-73°C
- Boiling Point:417.3 °C at 760 mmHg
- PKA:9.47±0.20(Predicted)
- Flash Point:206.2 °C
- PSA：40.54000
- Density:1.3 g/cm3
- LogP:1.96850
8-HYDROXYJULOLIDINE-9-ALDEHYDE(Cas 63149-33-7) Usage
InChI:InChI=1/C13H15NO2/c15-8-10-7-9-3-1-5-14-6-2-4-11(12(9)14)13(10)16/h7-8,16H,1-6H2
63149-33-7 Relevant articles
A novel colorimetric chemosensor for Cu2+ with high selectivity and sensitivity based on rhodamine B
Li, Changjiang,Xiang, Kaiqiang,Liu, Yunchang,Zheng, Yuchuan,Tian, Baozhu,Zhang, Jinlong
, p. 10169 - 10180 (2015)
9-formyl-8-hydroxy-2,3,6,7-tetrahydro-1H...
Synthesis of a NIR fluorescent dye and its application for rapid detection of HSO3? in living cells
Bu, Dandan,Li, Zhanxian,Ren, Haohui,Yu, Mingming,Zhang, Hongyan,Zhang, Qiang
, (2021/09/04)
SO2 and its derivatives (HSO3?, SO32?) p...
Three lysocolorimetric/lysofluorescent probes with mitochondria/lysosome dual targeting positioning
-
Paragraph 0044; 0047, (2021/05/01)
The invention discloses a preparation me...
A general strategy for selective detection of hypochlorous acid based on triazolopyridine formation
Zhang, Yanhui,Teng, Hao,Gao, Ying,Afzal, Muhammad Wasim,Tian, Jingye,Chen, Xi,Tang, Haoyang,James, Tony D.,Guo, Yuan
supporting information, p. 2917 - 2920 (2020/03/13)
Triazolopyridines are an important kind ...
A novel fluorescent probe with dual-sites for simultaneously monitoring metabolisms of cysteine in living cells and zebrafishes
Gan, Yabing,Li, Haitao,Liu, Meiling,Yao, Shouzhuo,Yin, Guoxing,Yin, Peng,Yu, Ting,Zhang, Youyu,Zhou, Li
, (2020/07/03)
Understanding cellular metabolism holds ...
63149-33-7 Process route
-
-
41175-50-2
8-hydroxyjulolidine
-
-
68-12-2,33513-42-7
N,N-dimethyl-formamide
-
-
63149-33-7
9-formyl-8-hydroxyjulolidine
| Conditions | Yield |
|---|---|
|
With
trichlorophosphate;
at 0 - 80 ℃;
for 1.25h;
Inert atmosphere;
|
97.6% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 4 ℃;
for 0.25h;
8-hydroxyjulolidine;
at 20 - 100 ℃;
for 1h;
|
94% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 4 ℃;
for 0.25h;
8-hydroxyjulolidine;
In
water;
at 4 - 100 ℃;
for 2.5h;
|
94% |
|
With
trichlorophosphate;
|
90% |
|
With
trichlorophosphate;
a) RT, 30 min, b) heating, 30 min;
|
87% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 0 ℃;
for 0.25h;
Inert atmosphere;
8-hydroxyjulolidine;
In
N,N-dimethyl-formamide;
at 0 - 20 ℃;
Inert atmosphere;
With
water;
In
N,N-dimethyl-formamide;
at 0 - 20 ℃;
for 0.25h;
Inert atmosphere;
|
84% |
|
8-hydroxyjulolidine; N,N-dimethyl-formamide;
With
trichlorophosphate;
at 4 - 100 ℃;
for 1h;
With
water;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 1.5h;
Further stages.;
|
80% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 0 - 20 ℃;
for 0.5h;
8-hydroxyjulolidine;
at 20 - 60 ℃;
for 1.5h;
|
78% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 0 ℃;
for 1h;
Inert atmosphere;
8-hydroxyjulolidine;
In
N,N-dimethyl-formamide;
at 0 - 20 ℃;
for 32h;
Inert atmosphere;
|
78.8% |
|
With
trichlorophosphate;
Reflux;
|
74% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
for 0.5h;
Cooling with ice;
8-hydroxyjulolidine;
at 20 - 100 ℃;
for 2h;
|
70.9% |
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 20 ℃;
for 0.5h;
Inert atmosphere;
8-hydroxyjulolidine;
at 20 - 80 ℃;
for 1h;
Inert atmosphere;
|
69.1% |
|
With
trichlorophosphate;
at 20 ℃;
for 1h;
Inert atmosphere;
Reflux;
|
67% |
|
With
trichlorophosphate;
|
63% |
|
With
trichlorophosphate;
In
N,N-dimethyl-formamide;
for 1h;
Yield given;
room temp., 30 min, heating 30 min;
|
|
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 20 ℃;
for 0.5h;
Inert atmosphere;
8-hydroxyjulolidine;
In
N,N-dimethyl-formamide;
at 20 - 60 ℃;
for 1h;
Inert atmosphere;
With
water;
In
N,N-dimethyl-formamide;
for 2h;
Inert atmosphere;
|
|
|
With
trichlorophosphate;
at 0 - 5 ℃;
|
|
|
With
trichlorophosphate;
at 0 - 5 ℃;
|
|
|
With
trichlorophosphate;
|
|
|
With
trichlorophosphate;
at 70 ℃;
for 1.75h;
Time;
Cooling with ice;
|
|
|
With
trichlorophosphate;
|
|
|
N,N-dimethyl-formamide;
With
trichlorophosphate;
for 0.5h;
Inert atmosphere;
8-hydroxyjulolidine;
In
N,N-dimethyl-formamide;
at 60 ℃;
for 12h;
Inert atmosphere;
|
0.9 g |
-
-
109-70-6
1.3-chlorobromopropane
-
-
591-27-5
m-Hydroxyaniline
-
-
63149-33-7
9-formyl-8-hydroxyjulolidine
| Conditions | Yield |
|---|---|
|
1.3-chlorobromopropane; m-Hydroxyaniline;
In
N,N-dimethyl-formamide;
at 70 ℃;
for 12h;
With
trichlorophosphate;
In
N,N-dimethyl-formamide;
at 100 ℃;
for 2.5h;
Cooling with ice;
|
59.9% |
63149-33-7 Upstream products
-
41175-50-2
8-hydroxyjulolidine
-
68-12-2
N,N-dimethyl-formamide
-
63468-83-7
8-methoxy-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinoline
-
536-90-3
m-Anisidine
63149-33-7 Downstream products
-
83179-50-4
9.9'-carbonylbis(1,2,4,5-tetrahydro-3H,6H,10H<1>benzopyrano<9,9a,1-gh>quinolazine-10-one)
-
129667-42-1
10-(4-nitrophenyl)-2,3,6,7-tetrahydro-11-oxo-1H,5H,11H-benzopyrano<6,7,8-i,j>quinolizine
-
85642-11-1
coumarin 545
-
55804-66-5
ethyl 11-oxo-2,3,6,7-tetrahydro-1H,5H,11H-pyrano[2,3-f ]-pyrido[3,2,1-ij]quinoline-10-carboxylate