TRIS(TRIMETHYLSILOXY)SILANE
Basic Information
- CAS No.:1873-89-8
Physical properties
Product Description
Manufacturer supply top purity TRIS(TRIMETHYLSILOXY)SILANE 1873-89-8 with GMP standards
- Molecular Formula:C9H28O3Si4
- Molecular Weight:296.662
- Appearance/Colour:clear colorless liquid
- Melting Point:<0°C
- Refractive Index:n20/D 1.386(lit.)
- Boiling Point:184.999 °C at 760 mmHg
- Flash Point:55 °C
- PSA:27.69000
- Density:0.852 g/cm3
- LogP:3.25810
TRIS(TRIMETHYLSILOXY)SILANE(Cas 1873-89-8) Usage
|
Application |
Gives highly stereoselective reduction of substituted cyclohexanones. |
InChI:InChI=1/C9H27O3Si4/c1-14(2,3)10-13(11-15(4,5)6)12-16(7,8)9/h1-9H3
1873-89-8 Relevant articles
1,1,1,5,5,5-HEXAMETHYLTRISILOXANE: PREPARATION AND SOME REACTIONS
Seyferth, Dietmar,Prud'homme, Christian C.,Wang, Wei-Liang
, p. 203 - 210 (1984)
1,1,1,5,5,5-Hexamethyltrisiloxane (I) wa...
ZUR SYNTHESE VON SILOXANEN III. INDUKTIVE SUBSTITUENTENKONSTANTEN FUER SILOXYRESTE; 29Si-NMR-SPEKTROSKOPISCHE UNTERSUCHUNGEN
Scheim, U.,Grosse-Ruyken, H.,Ruehlmann, K.,Porzel, A.
, p. 27 - 32 (1986)
For a series of siloxy groups at the sil...
Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols
Arzumanyan, Ashot V.,Goncharova, Irina K.,Novikov, Roman A.,Milenin, Sergey A.,Boldyrev, Konstantin L.,Solyev, Pavel N.,Tkachev, Yaroslav V.,Volodin, Alexander D.,Smol'Yakov, Alexander F.,Korlyukov, Alexander A.,Muzafarov, Aziz M.
supporting information, p. 1467 - 1471 (2018/04/12)
A highly efficient preparative method fo...
Symetrical hydroxyphenyl-s-triazine compositions
-
, (2008/06/13)
The invention is concerned with compound...
Untersuchungen zu Substituenteneffekten in Tris(methylorganophenylsiloxy)silanen (RMePhSiO)3SiH
Popowski, Eckhard,Kraft, Oliver,Kelling, Hans,Jancke, Harald
, p. 30 - 31 (2007/10/02)
-
Method for the cleavage of organic siloxanes, and products and applications thereof
-
, (2008/06/13)
A method for the cleavage of organosilox...
1873-89-8 Process route
-
-
107-46-0
Hexamethyldisiloxane
-
-
1873-89-8
1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]trisiloxane
| Conditions | Yield |
|---|---|
|
With
sulfuric acid; trichlorosilane;
In
water;
at 50 ℃;
for 0.5h;
|
75% |
-
-
1066-40-6
Trimethylsilanol
-
-
1873-89-8
1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]trisiloxane
| Conditions | Yield |
|---|---|
|
With
pyridine; trichlorosilane;
In
hexane;
at -70 - 25 ℃;
|
53% |
|
With
pyridine; trichlorosilane;
In
diethyl ether;
|
1873-89-8 Upstream products
-
75-77-4
chloro-trimethyl-silane
-
1066-40-6
Trimethylsilanol
-
18027-10-6
sodium trimethylsilanolate
-
107-46-0
Hexamethyldisiloxane
1873-89-8 Downstream products
-
17905-99-6
tris(trimethylsiloxy)silyl chloride
